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Metal–organic frameworks vs. buffers: case study of UiO-66 stability

Metal–organic frameworks vs. buffers: case study of UiO-66 stability

autor: Jan Demel | Led 25, 2021 | Publikace, Selected on HomePage

D. Bůžek,* S. Adamec, K. Lang, J. Demel Inorg. Chem. Front. 2021, Abstract: UiO-66 is a zirconium-based metal–organic framework (MOF) that has numerous applications. Our group recently determined that UiO-66 is not as inert in aqueous dispersions as previously...
UiO-66 – stability in aqueous environment and its relevance for organophosphate degradations

UiO-66 – stability in aqueous environment and its relevance for organophosphate degradations

autor: Jan Demel | Říj 16, 2018 | Publikace, Selected on HomePage

D. Bůžek, J. Demel, K. Lang* Inorg. Chem. 2018, 57, 14290-14297 Abstract: Zirconium-based metal-organic frameworks were recently investigated as catalysts for degradation of organophosphate toxic compounds, such as pesticides or chemical warfare agents. The most...
Phosphinic Acid Based Linkers: Building Blocks in Metal–Organic Framework Chemistry

Phosphinic Acid Based Linkers: Building Blocks in Metal–Organic Framework Chemistry

autor: admin | Čvc 24, 2018 | Publikace, Selected on HomePage

J. Hynek, P. Brázda, J. Rohlíček, M. G. S. Londesborough and J. Demel* Angew. Chem. 2018, 130, 5110 –5113 Abstract: Metal–organic frameworks (MOFs) are a chemically and topologically diverse family of materials composed of inorganic nodes and organic linkers bound...
Designing Porphyrinic COFs for the Photodynamic Inactivation of Bacteria

Designing Porphyrinic COFs for the Photodynamic Inactivation of Bacteria

autor: admin | Čvc 23, 2018 | Publikace, Selected on HomePage

J. Hynek, J. Zelenka, J. Rathouský, P. Kubát, T. Ruml, J. Demel and Kamil Lang ACS Appl. Mater. Interfaces 2018, 10, 8527-8535 Abstract: Microbial colonization of biomedical devices is a recognized complication contributing to healthcare-associated infections. One of...
Postsynthetic modification of a Zr-MOF at the SBU with diphenylphosphinic acid

Postsynthetic modification of a Zr-MOF at the SBU with diphenylphosphinic acid

autor: admin | Čvc 22, 2018 | Publikace

J. Hynek, S. Ondrušová, D. Bůžek, P. Kovář, J. Rathouský and J. Demel Chem. Commun., 2017, 53, 8557 Abstract: A zirconium metal–organic framework (MOF) PCN-222 was postsynthetically modified with diphenylphosphinic acid, resulting in an increased stability when...
Lanthanide-Porphyrin Hybrids: from Layered Structures to MOFs

Lanthanide-Porphyrin Hybrids: from Layered Structures to MOFs

autor: Jan Demel | Čvc 25, 2012 | Publikace

J. Demel, P. Kubát, F. Millange, J. Marrot, I. Císařová, K. Lang Inorg. Chem. 2013, 52, 2779-2786 Abstract:  Rare-earth layered hydroxides with intercalated tetrasulfonated porphyrins and corresponding to the chemical formula Ln2(OH)4.7(Por)0.33·2H2O (Ln = Eu3+, Tb3+;...
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